منابع مشابه
Applications of Ion Selective Electrodes
Enzyme sensor for organophosphorus insecticides organophosphorus hydrolase in a polymer membrane on a pH sensor is used to catalyse the hydrolysis of compounds with phoshate ester functionality. The detected [H+] change is proportional to the concentration of the phosphate ester insecticide. This is a good example of the use of an enzyme to give selectivity to a specific class of compounds. Unf...
متن کاملPolystyrene Based Silver Selective Electrodes
Silver(I) selective sensors have been fabricated from polystyrene matrix membranes containing macrocycle, Me6(14) diene.2HClO4 as ionophore. Best performance was exhibited by the membrane having a composition macrocycle : Polystyrene in the ratio 15:1. This membrane worked well over a wide concentration range 5.0×10–1.0×10M of Ag with a near-Nernstian slope of 53.0 ± 1.0 mV per decade of Ag act...
متن کاملComparison of the vanadyl-selective electrodes prepared by sol–gel and PVC membrane techniques
Sol-gel and polymeric membrane electrodes, based on thiacalix[4]arene as a neutral carrier, weresuccessfully developed for the detection of VO2+ in aqueous solutions. The sol-gel and PVCmembrane electrodes exhibited linear response with Nernstian slopes of 29.3 and 28.4 mV perdecade, respectively, within the vanadyl ion concentration ranges from 1.0 × 10-6 to 1.0 × 10-1mol dm-3 and from 1.0 × 1...
متن کاملWorking mechanism of ion-selective electrodes
A theory for the interpretation of the operation mechanism of ion-selective membrane electrodes is briefly outlined. The statements are based on the accumulated results concerning the electrochemical and spectrochemical behaviour of ion-selective membranes.
متن کاملDetermination of sodium with ion-selective electrodes.
The advent of ion-selective electrodes made possible the potentiometry of sodium in serum and plasma. These methods were based on dilution of serum, as done in flame photometry, and the results were identical. Analysis of whole blood precludes dilution and so "direct" potentiometry was developed. Results by this technique are variable but tend to compensate for the spurious hyponatremias found ...
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ژورنال
عنوان ژورنال: Journal of Chemical Education
سال: 1985
ISSN: 0021-9584,1938-1328
DOI: 10.1021/ed062p178.2